C1.16

Solubility

Indicative relationship: Activate 1 · Chemistry Chapters 1–2
KS3 science lesson

Solubility

Lesson focus: is a capacity under stated conditions, not the speed of dissolving.

Learning objective

Interpret solubility data and calculate on cooling.

Build on earlier learning

Solutions

Extend solution language to saturation and quantitative capacity.

Practical

How much solute dissolves

  1. Add one spatula of salt at a time to 50 cm³ of water, stirring until it dissolves.
  2. Stop when solid remains: the solution is saturated.
  3. Repeat with warmer water and compare the number of spatulas.

Record: A table of temperature against spatulas dissolved and a conclusion about solubility.

You will be successful when you can…

  • Define solubility and saturation.
  • Read a solubility curve.
  • Distinguish rate from capacity.
  • Calculate crystals produced on cooling.
KEY VOCABULARY

Words that carry the science

solubility
Maximum solute mass dissolving in a stated solvent amount under stated conditions.
saturated solution
Solution containing the maximum dissolved solute under stated conditions.
unsaturated solution
Solution able to dissolve more solute under stated conditions.
crystallisation
Formation of solid crystals from a solution.
dissolving rate
How quickly solute enters solution.
BUILD YOUR UNDERSTANDING

Read capacity from axes, units and temperature

01Units matter

A common unit is grams solute per 100 g water at a stated temperature. Read temperature and solvent mass before using data.

02Saturated is a boundary

Points on the curve are saturated; below are unsaturated. Above implies excess solid or supersaturation, depending on conditions.

03Rate is not solubility

Stirring and smaller grains can increase rate without changing final capacity. Temperature may change both, so experiments must measure them separately.

A graph of the solubility of potassium nitrate, in grams per 100 grams of water, against temperature from 0 to 100 degrees Celsius. The curve rises more and more steeply. A point on the curve is a saturated solution; a point below the curve is unsaturated.0102030405060708090100050100150200250saturated (on the curve)unsaturated (below the curve)potassium nitrateTemperature / °CSolubility / g per 100 g water
Figure · Approximate data for potassium nitrate. Read both axes and units. A point on the curve is saturated; a point below it is unsaturated. Solubility is a capacity at stated conditions; it is not the same as dissolving rate.
Interactive model

Solubility curves

Add solid to 100 g of water. Below the curve it all dissolves; on the curve the solution is saturated; any more stays as solid. Press play to cool the solution and watch crystals form.

60 °C60 g potassium nitrate in 100 g waterAll dissolved (unsaturated)

Controls

Solid
60 g
60 °C
Solubility at this temperature110.0 g per 100 g water
Dissolved60.0 g
Left as solid0.0 g

Data from standard solubility tables. Sodium chloride hardly changes with temperature, so cooling gives almost no crystals.

Potassium nitrate solubility rises steeply from 13 g at 0 °C to 246 g at 100 °C; sodium chloride stays near 36 to 40 g.020406080100050100150200250Your mixPotassium nitrateSodium chlorideTemperature / °CSolubility / g per 100 g water
WORKED EXAMPLE

Crystals on cooling

is 80 g/100 g water at 60 °C and 30 g/100 g water at 20 °C. A contains 100 g water.

  1. At 60 °C, 80 g is dissolved.
  2. At 20 °C, only 30 g remains dissolved.
  3. Difference = 80 − 30.
  4. 50 g crystals can form, assuming no water loss.

How to make the reasoning visible: Use the same solvent mass at both temperatures.

LEARN BY DOING

Solubility dataset

Values are illustrative and use g solute per 100 g water.

Temperature / °CSolubility / g40 g addedStatus
203040 g30 g dissolved; 10 g excess
405040 gUnsaturated
608040 gUnsaturated
80110110 gSaturated
  1. At 20 °C, how much remains undissolved from 40 g?

  2. Does stirring change the 20 °C solubility?

  3. Use the dataset. What happens to the solubility of this solid as the temperature rises?

RETRIEVE · APPLY · CHECK

Check your understanding

Answer from memory, then check against the suggested answer.

What is solubility?

What is saturated solution?

What is unsaturated solution?

What is a saturated solution?

Does stirring change how much solute can dissolve?

Apply the idea

A hot saturated solution cools without water loss. Why do crystals form?

Stretch and challenge

How many grams crystallise if 50 g water cools between the example temperatures?

A hot saturated solution is cooled. Why do crystals appear?

Exam Question Practice

C1.16Calculate4 marks

Exam Question Practice

Mark points shown after marking

The solubility of a salt falls from 70 g to 25 g per 100 g of water as a solution cools. The saturated solution contains 200 g of water.

Calculate the mass of crystals that form. Show your working.

(4)
g

Total for this question: 4 marks

Command word: Write the capacity change first, then scale for solvent mass.

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