C6.8

Electronic configuration

Indicative relationship: Edexcel International GCSE Chemistry · Principles of Chemistry and selected Group 1 content
KS3 science lesson

Electronic configuration

Lesson focus: Electron arrangements of the first 20 elements reveal number, outer-shell electron count and recurring chemical patterns.

Learning objective

Deduce first-20 electron configurations and relate them to position and formation.

Build on earlier learning

Groups and periods

Year 8 used groups and periods. This lesson explains those patterns using electron arrangement.

You will be successful when you can…

  • Write first-20 configurations.
  • Relate shells to periods.
  • Relate outer electrons to main groups.
  • Predict simple ion charges.
KEY VOCABULARY

Words that carry the science

electron shell
A simplified energy-level region occupied by electrons.
electronic configuration
The arrangement of electrons among shells or energy levels.
period
A horizontal row in the Periodic Table.
group
A vertical column whose main-group elements share outer-shell patterns.
valence electron
An electron in the outer occupied shell involved in bonding and reactions.
ion
A charged particle formed when electrons are lost or gained.
BUILD YOUR UNDERSTANDING

Nuclear charge determines electron count

01Nuclear charge determines electron count

A neutral atom has one electron per proton. For the first 20 elements, the school shell model fills 2 in the first shell, then 8, then 8 before starting the fourth.

Examples are sodium 2,8,1; chlorine 2,8,7; calcium 2,8,8,2. This is a useful introductory model, not a complete quantum description.

02Position follows occupied and outer shells

The number of occupied shells gives the . For main-group elements, the number of outer-shell electrons connects to position: Group 1 has one and Group 7 has seven; Group 0 has a full outer shell.

Helium is in Group 0 with two electrons because its first shell is full, despite not having eight.

03Atoms form ions through electron transfer

Metals such as sodium lose outer electrons to form positive ; non-metals such as chlorine gain electrons to form negative ions. The nucleus is unchanged.

Na forms Na⁺ with 2,8; Mg forms Mg²⁺ with 2,8; Cl forms Cl⁻ with 2,8,8. A full outer shell is a pattern, not a force or conscious goal.

Three cards show sodium, chlorine and calcium shell configurations, their periods and groups, and the configurations of their common ions.Na2,8,1Period 3 · Group 1Na⁺: 2,8Cl2,8,7Period 3 · Group 7Cl⁻: 2,8,8Ca2,8,8,2Period 4 · Group 2Ca²⁺: 2,8,8ion formation changes electrons—not the nucleus
Figure · Occupied shells give the period; outer electrons link main-group position and likely simple ion charge.
Interactive model

Electron shells

Electrons fill the shells nearest the nucleus first: up to 2 in the first shell, then 8, then 8. The number of shells gives the period, and the outer electrons give the group.

6p6nC2, 4

Controls

6: Carbon
Protons, neutrons, electrons6, 6, 6
Electron arrangement2, 4
Period and groupPeriod 2, group 4

Neutron numbers are for the most common isotope. Group 0 elements have full outer shells, so they are unreactive.

The number of outer electrons rises from 1 to 8 across each period, then drops back to 1 at the start of the next period.024681012141618200123456789Outer electronsCarbon (selected)Atomic numberOuter-shell electrons
WORKED EXAMPLE

Place an element from its configuration

An atom has 2,8,3.

  1. Total electrons = 13, so a neutral atom has atomic number 13: aluminium.
  2. Three occupied shells place it in Period 3.
  3. Three outer electrons place this main-group element in Group 3 in the specification convention.
  4. It can lose three electrons to form Al³⁺ with configuration 2,8.

How to make the reasoning visible: Configuration predicts both table position and likely simple ion charge.

LEARN BY DOING

Read patterns in the first 20

Complete the table using atomic number and shell arrangement.

ElementConfigurationPeriodLikely ion
lithium, Z=32,12Li⁺
oxygen, Z=82,62O²⁻
potassium, Z=192,8,8,14K⁺
calcium, Z=202,8,8,24Ca²⁺
  1. Why are lithium and potassium in the same group?

  2. What changes from Na to Na⁺?

RETRIEVE · APPLY · CHECK

Check your understanding

Answer from memory, then check against the suggested answer.

What determines period in the shell model?

What do Group 1 atoms share?

How does a cation form?

Apply the idea

An element has configuration 2,8,7. Predict its period, group and ion.

Stretch and challenge

Why is “atoms react to become stable” an incomplete explanation?

Exam Question Practice

C6.8Explain6 marks

Exam Question Practice

Mark points shown after marking

Sodium (atomic number 11) and chlorine (atomic number 17) react to form sodium chloride.

(a)

Explain how the electronic configurations relate to their positions in the Periodic Table.

(3)
(b)

Explain how they form ions.

(3)

Total for this question: 6 marks

Command word: For , connect each configuration feature to one table position or ion outcome.

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