C6.7

Atomic structure

Indicative relationship: Edexcel International GCSE Chemistry · Principles of Chemistry and selected Group 1 content
KS3 science lesson

Atomic structure

Lesson focus: Atoms contain a tiny positive nucleus of and surrounded by ; share proton number but differ in neutron number.

Learning objective

Determine subatomic particle numbers and calculate relative atomic mass from isotopic abundance.

Build on earlier learning

Atoms

Year 7 introduced atoms. This lesson develops the nuclear model, isotopes and weighted relative atomic mass.

You will be successful when you can…

  • State particle charges and relative masses.
  • Use atomic and mass numbers.
  • Define isotope correctly.
  • Calculate weighted Ar.
KEY VOCABULARY

Words that carry the science

proton
Nuclear particle with relative charge +1 and relative mass 1.
neutron
Nuclear particle with charge 0 and relative mass 1.
electron
Particle with relative charge −1 and very small relative mass.
atomic number
Number of protons in an atom nucleus.
mass number
Total number of protons and neutrons in one isotope.
isotope
Atoms of one element with equal proton number but different neutron number.
BUILD YOUR UNDERSTANDING

The nucleus contains nearly all atomic mass

01The nucleus contains nearly all atomic mass

and occupy a tiny nucleus. occupy regions around it. Proton and neutron relative masses are about 1; electron mass is approximately 1/1836 of a proton and treated as negligible in mass-number calculations.

Z equals proton number. A equals protons plus neutrons, so neutrons = A − Z. A neutral atom has equal proton and electron numbers.

02Isotopes are the same element

have the same proton number, so they are one element, but different neutron numbers. Their electron arrangements—and therefore chemical behaviour—are usually very similar.

Isotopes can differ in mass and nuclear stability. Mass number belongs to one isotope and is a whole number.

03Abundance produces a weighted mean

Calculate Ar = Σ(isotopic mass × abundance) ÷ Σabundance. Percentage abundances sum to 100, but the general denominator prevents hidden mistakes.

The resulting Ar can be non-integer because it averages different isotopes; no individual atom has the average neutron count.

A carbon atom has a nucleus of six protons and six neutrons, with two electrons in the first shell and four in the second. Labels point to a proton, a neutron, the nucleus, an electron and an electron shell. A table gives relative charge and mass: proton +1 and 1, neutron 0 and 1, electron −1 and very small. A box shows the relative atomic mass of chlorine from 75% chlorine-35 and 25% chlorine-37: 35.5.proton (+)neutronnucleuselectron (−)shellcarbon atom, not to scale: the nucleus is about100 000 times narrower than the atomparticlechargemassproton+11neutron01electron−1very smallrelative charge and relative massRelative atomic mass of chlorine75% chlorine-35 and 25% chlorine-37(35 × 75 + 37 × 25) ÷ 100= 35.5
Figure · Atomic number fixes element identity. Mass number counts nucleons; relative atomic mass averages an isotope population.
Interactive model

Build an atom

The number of protons decides the element. Neutrons add mass but not charge; atoms of one element with different numbers of neutrons are isotopes. Electrons fill shells (2, then 8, then 8); if they do not match the protons, you have an ion.

73LiLithium

Proton Neutron Electron

Controls

3 (Lithium)
4
3
ElementLithium (Li), atomic number 3
Mass number3 + 4 = 7
Chargeneutral atom
NeutronsMost common form
Electron shells2, 1
WORKED EXAMPLE

Calculate chlorine Ar

A sample is 75% chlorine-35 and 25% chlorine-37.

  1. Multiply masses by abundances: 35 × 75 and 37 × 25.
  2. Add weighted values: 2625 + 925 = 3550.
  3. Divide by total abundance: 3550 ÷ 100.
  4. Ar = 35.5.

How to make the reasoning visible: 35.5 is a weighted population mean, not the mass number of one chlorine atom.

LEARN BY DOING

Decode nuclear notation

Use proton and mass numbers to complete each particle account.

SpeciesProtonsNeutronsElectrons
²³Na atom (Z=11)111211
²⁴Mg²⁺ (Z=12)121210
³⁵Cl⁻ (Z=17)171818
³⁷Cl atom (Z=17)172017
  1. Why are chlorine-35 and chlorine-37 isotopes?

  2. Which particle number changes when an ion forms?

RETRIEVE · APPLY · CHECK

Check your understanding

Answer from memory, then check against the suggested answer.

What is atomic number?

How is neutron number found?

Define isotope.

Apply the idea

Element X has isotopes 10 (20%) and 11 (80%). Calculate Ar.

Stretch and challenge

Why do isotopes react similarly but diffuse at slightly different rates?

Exam Question Practice

C6.7Calculate5 marks

Exam Question Practice

Mark points shown after marking

Copper is 69.2% copper-63 and 30.8% copper-65.

(a)

Calculate the relative atomic mass of copper. Give your answer to 1 decimal place.

(4)
(b)

Explain why the relative atomic mass is not a whole number.

(1)

Total for this question: 5 marks

Command word: For , show the weighted products and denominator, then interpret the decimal.

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