C6.2

Diffusion and changes of state

Indicative relationship: Edexcel International GCSE Chemistry · Principles of Chemistry and selected Group 1 content
KS3 science lesson

Diffusion and changes of state

Lesson focus: Changes of state alter particle energy, movement and arrangement without changing chemical identity; produces net spreading from random motion.

Learning objective

Explain state interconversions and diffusion using energy transfers and random particle motion.

Build on earlier learning

Diffusion

Year 7 introduced diffusion. This lesson connects it to temperature, random motion and state changes.

You will be successful when you can…

  • Name six state changes.
  • Explain energy changes.
  • Explain diffusion as net movement.
  • Distinguish physical from chemical change.
KEY VOCABULARY

Words that carry the science

melting
Change from solid to liquid.
boiling
Rapid vaporisation throughout a liquid at its boiling point.
evaporation
Vaporisation from a liquid surface below or at its boiling point.
condensation
Change from gas to liquid.
sublimation
Direct change from solid to gas.
deposition
Direct change from gas to solid.
diffusion
Net movement of particles from higher to lower concentration due to random motion.
BUILD YOUR UNDERSTANDING

State changes transfer energy without making a new substance

01State changes transfer energy without making a new substance

Heating can cause , , or . Cooling can cause , freezing or . During these , chemical identity is retained.

Energy supplied increases internal energy. At a change-of-state temperature, transferred energy is used to overcome particle attractions rather than produce a temperature rise.

02Boiling and evaporation are not synonyms

Evaporation occurs at a liquid surface and can happen below the boiling point when higher-energy particles escape. Boiling occurs throughout a liquid when vapour bubbles form at a characteristic temperature for the pressure.

Evaporation cools the remaining liquid because escaping particles carry away more energy than average.

03Random motion creates net diffusion

Particles move randomly in all directions. Where concentration differs, more particles cross from the crowded region per second, creating down the concentration gradient.

Higher temperature increases particle speeds and usually increases rate. Lower particle mass can also increase gas diffusion rate under comparable conditions.

Solid, liquid and gas are joined by paired arrows. Melting, boiling and sublimation take in energy; freezing, condensing and deposition give out energy. A second panel shows many particles on the left of a box and few on the right, with net diffusion from higher to lower concentration.solidliquidgasmeltingfreezingsublimationdepositionboilingcondensingenergy taken inenergy given outNet diffusionhigher concentrationlower concentration
Figure · State changes alter arrangement and energy without changing identity. Diffusion is net spreading caused by random motion.
Interactive model

Heating curve of water

Ice is heated steadily. While it melts and while it boils, the temperature stays the same: the energy is breaking the forces between particles.

Controls

0.0 min
Temperature-20 °C
StateIce warming up
Temperature rises from −20 °C to 0 °C, stays flat while the ice melts, rises to 100 °C, stays flat while the water boils, then rises again.036912151821−20020406080100120-20 °Cmeltingboiling (shortened)Time / minutesTemperature / °C
Interactive model

Diffusion in a liquid

A drop of dye spreads out because its particles are knocked about by water particles. Warmer water particles move faster, so the dye spreads faster.

Where the dye was addedFar side

Controls

20 °C
Dye: where the dye was added50
Dye: far side0
Net movementFrom high to low concentration
The number of particles on the right rises quickly at first, then levels off when the two sides are about equal.010203040506001020304050Time / sDye particles on the right
WORKED EXAMPLE

Explain a cooling curve plateau

A liquid cools and its temperature remains constant while it freezes.

  1. Particles lose internal energy to the surroundings.
  2. At the freezing point, particles become more ordered.
  3. Energy is released as attractions form or strengthen.
  4. Temperature stays constant until the state change is complete.

How to make the reasoning visible: Constant temperature during freezing does not mean no energy transfer occurs.

LEARN BY DOING

Connect observations to mechanisms

Interpret each physical process without inventing new substances.

ObservationProcessEnergy transferParticle account
puddle disappears below 100 °Cevaporationfrom surroundingssurface particles escape
steam forms dropletscondensationto surroundingsparticles slow and come closer
iodine solid forms purple vapoursublimationinto sampleparticles separate into gas
gas colour spreadsdiffusionnot a state changerandom motion gives net spreading
  1. Why does warming speed diffusion?

  2. Why is condensation physical?

RETRIEVE · APPLY · CHECK

Check your understanding

Answer from memory, then check against the suggested answer.

What is gas to liquid?

Where does evaporation occur?

Define diffusion.

Apply the idea

Why does wet skin feel colder in moving air?

Stretch and challenge

At diffusion equilibrium, have particles stopped?

Exam Question Practice

C6.2Explain5 marks

Exam Question Practice

Mark points shown after marking

A smell spreads through a room faster from a warm liquid than from the same liquid when cold.

(a)

Explain why more vapour forms from the warm liquid.

(2)
(b)

Explain why the smell spreads faster.

(3)

Total for this question: 5 marks

Command word: For , connect temperature to both production of vapour and its subsequent diffusion.

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